AMMONIA DEPOSITION PRECIPITATION PROCESS FOR PRODUCING A COPPER-NICKEL/GAMMA-ALUMINA CATALYST, SAID CATALYST AND ITS USE IN THE CONVERSION OF EXHAUST GASES

Patent number:

US2021394162

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A process for the production of a catalyst comprising the steps of: dissolving the requisite quantities of copper nitrate and nickel nitrate in de-ionised water to provide a sub-0.30 molar aqueous solution of copper nitrate and nickel nitrate together in the ratio required; providing an ammoniacal solution by adding concentrated aqueous solution of ammonia in a quantity equal to between six and ten times the quantity required to realise both a 1:6 molar ratio for Cu2+ to ammonia and a 1:6 molar ratio for Ni2+ to ammonia; loading gamma alumina with 1 to 30 percent w/w of copper and nickel in a weight ratio of nickel to copper of 1:5 to 2:1 by suspending the requisite quantity of gamma alumina in said ammoniacal solution to achieve the required loading of copper and nickel; stirring the resulting gamma alumina suspension for at least 4 h at room temperature; then the volatile components evaporate under ambient conditions leaving dry loaded gamma alumina, which is calcined at a temperature of at least 260 degrees centigrade for at least 30 min with a constant heating up rate; a catalyst or catalyst mixture, the catalyst or each catalyst in the catalyst mixture being obtainable by the above-mentioned process; and the use of the catalyst or catalyst mixture for the conversion of exhaust gases from an internal combustion engine into carbon dioxide, water and nitrogen.

Countries:
Belgium
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Centers:
UNIVERSITY OF ANTWERP
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Sectors:
Automotive & Rail
Subsectors:
TRL Level:
TRL 3 – experimental proof of concept
BRL Level:
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Applications

New automotive catalyst for conversion of exhaust gases

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